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Toluene diisocyanate CAS#26471-62-5

Toluene diisocyanate CAS#26471-62-5

Basic Information

Basic Information

CAS No.: 26471-62-5
Molecular Formula: C9H6N2O2
Molecular Weight: 174.15614

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Product Details

Toluene diisocyanate (TDI) is an aromatic diisocyanate that typically appears as a clear to pale yellow liquid with a sharp, pungent odor. It is insoluble in water but miscible with most common organic solvents.

TDI (CAS No. 26471-62-5) consists of two isomers: toluene-2,4-diisocyanate (2,4-TDI, CAS No. 584-84-9) and toluene-2,6-diisocyanate (2,6-TDI, CAS No. 91-08-7). Commercial TDI is supplied in various isomer ratios, with an 80:20 blend of 2,4-TDI and 2,6-TDI being the most common. TDI is widely used in the chemical industry and has historically accounted for a substantial share of the global isocyanate market.

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Toluene diisocyanate Chemical Properties

Melting point 19.5~21.5℃
Boiling point 247℃
density 1.22
vapor pressure 0.03 hPa ( 20 °C)
refractive index 1.5660 to 1.5700
Fp 137 °C
storage temp. Store below +30°C.
solubility miscible with Ether,Acetone,Benzene
form clear liquid
color Colorless to Light yellow
OdorSharp, pungent odor
explosive limit0.9-9.5% (v/v)
Water Solubility 124mg/L at 25℃
InChI1S/C9H6N2O2/c1-7-2-3-8(10-5-12)4-9(7)11-6-13/h2-4H,1H3
InChIKeyDVKJHBMWWAPEIU-UHFFFAOYSA-N
SMILESN(=C=O)c1c(ccc(c1)N=C=O)C
LogP3.43 at 22℃
CAS DataBase Reference26471-62-5(CAS DataBase Reference)
IARC2B (Vol. 39, Sup 7, 71) 1999
EPA Substance Registry SystemToluene diisocyanate (26471-62-5)
Risk Statements 26-36/37/38-40-42/43-52/53
Safety Statements 23-36/37/39-45-24/25
RIDADR 2078
WGK Germany WGK 2
RTECS NQ9490000
Autoignition Temperature620°C
TSCA TSCA listed
HazardClass 6.1(a)
PackingGroup II
HS Code 29291090
Storage Class6.1A - Combustible, acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard ClassificationsAcute Tox. 1 Inhalation
Aquatic Chronic 3
Carc. 2
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1A
STOT SE 3
Hazardous Substances Data26471-62-5(Hazardous Substances Data)
ToxicityA designated hazardous waste (EPA). It is a colorless to yellow solid, melting at about 20°C. TDI and MDI (diphenylmethane diisocyanate) are used in the manufacture of polyurethane foams by reaction with polyhydroxy compounds. These foams are used for insulation, upholstering, etc. Exposure is commonly by inhalation of the vapor. Both TDI and MDI can cause irritation of eyes and mucous membranes, in severe cases leading to pulmonary edema. Sensitization to TDI is common and frequently rapid, leading to an allergic reaction and some loss of lung function. In the United Kingdom, the threshold limit value is 0.02 ppm for not more than 20 min, or 0.005 ppm for 8 h.


Product Application of Toluene Diisocyanate CAS#26471-62-5

The isocyanate groups in toluene diisocyanate (TDI) react with hydroxyl groups to form urethane linkages. This property makes TDI an important raw material for manufacturing flexible polyurethane foams used in furniture, bedding, automotive seats, and seating systems for commercial transportation.

TDI is also used to produce polyurethane elastomers for applications such as automotive bumper covers, industrial rollers, sports footwear, and various mechanical products. In addition, it serves as a raw material for coatings, including metal coatings, wood coatings, and high-performance anticorrosion coatings.

Rigid polyurethane foam based on TDI is used in household refrigerators and residential construction, including wall sheathing and commercial roofing. Spray-applied rigid polyurethane foam formulated with TDI can also provide insulation for truck trailers, railway freight cars, and overseas shipping containers. Furthermore, moisture-curing TDI-based coatings are used as sealants and floor finishes for wood and concrete surfaces.

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