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Toluene diisocyanate

Toluene diisocyanate

Basic Information

CAS No.: 26471-62-5
Molecular Formula: C₉H₆N₂O₂
Molecular weight: 174.16

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Product Details

Toluene Diisocyanate (TDI) is an aromatic diisocyanate widely used as a key raw material in polyurethane manufacturing. Its reactive isocyanate groups readily react with polyols and other active-hydrogen compounds to form polyurethane materials with a wide range of properties.

Chemical Properties

ItemSpecification
Chemical NameToluene Diisocyanate
CAS No.26471-62-5
EC No.247-722-4
AbbreviationTDI
SynonymsToluylene Diisocyanate; 4-Methyl-m-phenylene Diisocyanate; TDI
Chemical FormulaC₉H₆N₂O₂
Molecular Weight174.16 g/mol
Chemical ClassOrganic Chemical
Chemical TypeAromatic Diisocyanate
Isomer CompositionTypically a mixture of 2,4-TDI and 2,6-TDI
AppearanceColorless to light-yellow clear liquid
OdorSharp / pungent odor
Melting PointApprox. 12–14°C
Boiling PointApprox. 247°C at atmospheric pressure
DensityApprox. 1.22 g/cm³ at 20°C
Flash PointApprox. 132–137°C
Vapor PressureApprox. 0.03 hPa at 20°C
Water SolubilityReacts with water
SolubilitySoluble in many organic solvents
Autoignition TemperatureApprox. 620°C
Main Chemical FunctionReactive diisocyanate used in polyurethane production
Main ApplicationsPolyurethane foams, elastomers, coatings, adhesives and sealants


Safety Information

ItemSafety Information
Hazard ClassificationAcute Toxicity; Skin Irritation; Eye Irritation; Skin Sensitization; Respiratory Sensitization; Specific Target Organ Toxicity; Carcinogenicity; Aquatic Chronic Hazard
Signal WordDanger
GHS PictogramsGHS06 – Toxic / GHS08 – Health Hazard
H330Fatal if inhaled
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
H412Harmful to aquatic life with long-lasting effects
Inhalation HazardAvoid breathing vapors, mist or aerosols. Inhalation may cause severe respiratory effects and sensitization.
Skin ContactMay cause irritation and allergic skin reactions. Avoid direct contact.
Eye ContactCauses serious eye irritation. Use suitable eye and face protection.
Respiratory SensitizationMay cause respiratory sensitization and asthma-like symptoms in sensitive individuals.
HandlingHandle only with adequate ventilation. Avoid generating vapors, mist or aerosols.
Personal ProtectionChemical-resistant gloves, protective clothing and eye/face protection. Appropriate respiratory protection may be required.
Moisture SensitivityReacts with water and moisture. Keep containers tightly closed and protected from moisture.
StorageStore in a cool, dry and well-ventilated area. Protect from heat, moisture, light and incompatible materials.
Emergency ResponseMove exposed persons to fresh air and seek immediate medical attention in case of inhalation exposure or breathing difficulty.
Environmental PrecautionPrevent uncontrolled release into drains, soil or water.
Safety DocumentationAlways refer to the latest supplier SDS and applicable local regulations before handling or transportation.

Product Applications

01 — Flexible Polyurethane Foams

TDI is primarily used in the production of flexible polyurethane foams for furniture, mattresses, bedding, automotive seats and other cushioning applications.

02 — Polyurethane Elastomers

TDI is used to produce polyurethane elastomers for automotive components, industrial rollers, mechanical parts, footwear and other applications requiring flexibility and durability.

03 — Polyurethane Coatings

TDI is used as a reactive raw material for polyurethane coatings, including automotive finishes, wood coatings, protective coatings and high-performance industrial coatings.

04 — Adhesives & Sealants

TDI can be used in the formulation of polyurethane-based adhesives and sealants, providing strong bonding performance and good mechanical properties.

05 — Automotive Applications

TDI-based polyurethane materials are widely used in automotive seating, cushioning materials, interior components, elastomers and protective coatings.

06 — Furniture & Bedding

Flexible polyurethane foams produced with TDI are commonly used in mattresses, sofas, cushions, furniture padding and other comfort products.

07 — Construction & Insulation

TDI-based polyurethane materials can be used in selected insulation, sealing and protective applications within the construction industry.

08 — Industrial Materials

TDI is also used in the production of polyurethane materials for industrial equipment, mechanical components, protective coatings and specialty applications.


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